manufacturers who have transported nitroglycerine in large quantities, and on the other hand, that those who manufacture and use nitroglycerine outside of the patent greatly outnumber the operators under the patent. The second point of coincidence suggests that Nobel's nitroglycerine undergoes a change after its manufacture. actual change had been going on in one or more of the pack- But there are those, and we are among them, who believe they have a reasonable clew to all the mystery of nitroglycerine; this c'ew they find in its chemical nature. Nitroglycerine is a sort of gunpowder, in which three atoms of the monatomic radical, nitryl (NO) serves as the nitre, and the glycerin residue (CH.O3) as the combustible part. The radical NO, is a remarkably concentrated and powerful oxidizer, and thus GLASS is commonly supposed to be one of the most gives to the organic compounds in which it has a unchangeable of chemical compounds, and that its single place a character of instability and danger. In pure been shown by Mr. T. Gaffield, of Boston, that nearly weak point is its frangibility. It has, however, recently nitroglycerine C.H.(NO2)30, the oxygen is brought very near to its antagonistic elements, and needs but all kinds of window glass, at least, become altered in little to provoke a contest which may terminate in color, and that the change is not superficial but extends an instant or be prolonged indefinitely; but the conwherever the light penetrates. Some samples show a test once begun it is irrepressible, unless by some out- change in a few hours of exposure, while others hold side interference. The possible products of a slow in-out for years. The tints seem to be limited to purples ternal oxidation are numerous, and it is pretty certain and yellows, the purples rupning from pale lavender into that some of these products are more unstable than the the lilac, mulberry, flesh, amethyst, rose, violet, pink, nitroglycerine itself. The oxdaition is of course acand deep purple, and the yellows through all shades of companied by heat, and if this heat be retained the has found that glass which has been stained by sunlight lemon to the brightest gold color. M. Pelouse rate of oxidation will be increased, and the exploding temperature will at last be reached. In short, here is light is bleached by an exposure to a red heat, and that the successive coloring and bleaching may be carried on a case of spontaneous combustion, which differs from ordinary cases in the fact that NO, takes the place of air. indefinitely. The facts in the case are certainly curious, Thus on theoretical grounds the character of nitroglyce- and photographers and greenhouse proprietors have rine may be predicted. opportunities to learn that they are of practical imporAll such considerations of theory are confirmed by tance; indeed it is not at all improbable that they may lead to some useful improvements in the arts. Indeed, before the theory was experience. Mr. possible we had the facts. Gaffield has given a hint, by making pretty designs in Sombrero, de Vrij, Frankland, and other investigators of nitroglycerine, more the sensitive glass, following the method of photothan twenty years ago, exhibited all its dangerous graphic printing, and perhaps has thus inaugurated a properties. That it is liable to a dangerously spontane-retical interest, involving such questions as what are new art of photography. The subject is of great theoous change is susceptible of simple and complete demon- the chemical reactions which accompany the changes, stration, and no one who will witness it without pre- and what is the character of the movements in the injudice can fail to find a satisfactory explanation of the terchange of atoms in dry solids like glass. Although mystery of nitroglycerine. There are two facts which it is especially desirable Mr. Gaffield was not the first to discover the coloring of to remember 1st. The spontaneous change once be- glass by light, he has so diligently and so laboriously gun in simple nitroglycerine will inevitably terminate explored the subject, that it fairly belongs to him, and in explosion, if the heat of oxidation be confined. 2d. his name will be identified with it for all time. He has Changed or impure nitroglycerine will explode at lower used a considerable part of his leisure for the past six temperatures and with less force of concussion than years in the investigation, and with unflagging interest pure nitroglycerine. Yet it has been persistently dehe is st ll planning and carrying on experiments. We clared that commercial nitroglycerine is not at all lia- spection of his samples of glass and of photographs, to are able, from a recent interview with him and an inble to spontaneous change, that it will not explode by a heat of less than 360 deg. Fahr., and only by an extra-testify to his intelligent industry and enthusiasm in the ordinary concussion. Pretty successful attempts were made in nearly all the cases of disasters which were judicially investigated to divert attention from the dangerous character of nitroglycerine by suggestions of anything else which was possible. It was represented that the Greenwich street explosion occurred because a tailor rather than an engineer had charge of the box, although neither the poor tailor nor any other person had opened it for months when it exploded; that the explosion at Aspinwall originated with percussion caps supposed to be on board the vessel destroyed, and that the Hudson Co. explosion was caused by a workman thrusting a red-hot iron into the can, or by the pressure of vapor in the can generating the exploding heat. The application of the chemical theory to the Ohio explosion is simple and satisfactory: The spontaneous m: er. Shoe Blacking. BLACKING, like cold punch, seems to be made up of incompatibles. Punch calls for fiery whiskey and ice (hot and cold); and sugar and lemon (sweet and sour). The receipts for blacking prescribe boneblack, composed of bone ash, say five parts (white), and carbon one part (black); oil of vitriol (sour), and molasses (sweet); and finally oil and water. Yet each of these ingredients has its specific and important office. The boneblack furnishes the blackness and the powder (carbonate and phosphate of lime), which, with the aid of the oil of vitriol, blows up, disintegrates, and pulverizes the tough, bony structure; the molasses provides for the shining, and the oil and water temper and preserve the consistercy needed for use. Thus the heterogeneous elements Kindly harmonize with each other and unite in producingents with anti-hydro matter, so as to render the game, and the igniting the happy result. It is worthy of remark that there is no free sulphuric acid in blacking, and that the sulphuric id of black ng is innocent of the crime with which it ire oa hed, of injuring the leather. The Sulphuric acid wholly combines with the lime of the boneblack, and tus, in effect, is put out of existence. Superphosphate, of line is, however, set tree in the chemical reaction, and proof is in order of any effect thereby, good or bad, ou the leather. Butter from Milk. surfaces and matches prepared therewith, wet and damp proof. 24. The manufacture of friction-igniting chemicals and ingredients for safety matches and their igniting surfaces, with the anti-hydro inatter or Compound herein mentioned, and applying the sene directly to or upon the natural surface of the material of boxes, match-containers, or match igniters of metal, china, stone, carthenware, or other similar materials, Sd. The manufacture of other match igniting chemicals, with the antihydro matter or compound herein mentioned, and applying the same to matches: 89,707.-PREPARING RESIN SIZE FOR USE IN PAPER-MAKING. Thomas Gray, of London, England. Patented in France June 30, 1868. I claim 1st. The improved process for making size, by first bleaching the resin in a solution of warm water and salt of soda, or other alkaline salt, and mixing the same with & solution of chloride of sodium, under the conditions substantially as and for the purpose specifled. 2d. Size prepared by the herein described process as a new article of manufacture, substantially as and for the purpose specined. 83,730.-APPARATUS FOR CARBURETING AIR.-Joseph Richard, assignor to himself and G. W. Baker, New York City. Antedated Oct. 28, 1868. I claim 1st. The arrangements and combination of the inclined shelves e, el, c2, 3, and absorbing sheets, i, 11, 12, 13, the upper edges of which dip into the troughs, d, di, d2, da, substantially as and for the purpose described. A PROBLEM, Something like that of how to extract blood from turnips, has, for several inonths past, been puzzling the chemical wits of the country. It is no less than how to produce one pound of butter out of a pint of milk and a chemical. That the problem is solved was put forth with considerable persistence by circulars and advertisements in newspapers, and oppor-e, el, 2, 3, absorbing shots, i, 11, 12, 13, and troughs, d, di, dz, d3, contunities have been abundant for procuring information CD an investment of one dollar and upward in the chemical or in a receipt. "The Patent Butter Associa-83,733.-RECOVERING WASTE ALKALIES FROM PAPER-STOCK 24. The vertically-adjustable rods, g, g', in combination with the shelves AND OTHER FIBRES.-Carl Dietrich Julius Seitz, Bury, I claim 1st. The general system or mode of treating the waste liquors resulting from the preparation of bamboo, cane, Esparto, grass, alt straw, or other similar fibrous substance, as and for the purpose herein set forth. tion" of this city, or some needy young man under 2d. The system or mode of mixing the concentrated waste liquors with I claim the composition, substantially as and for the purpose above set forth. 83,743.-CHARGING GASES WITH VAPORS OF HYDRO-CARY CON LIQUID.-Cyrus M. Williams, assignor to Henri L. Stu art, New York City. I claim, 1st, a gas-holder, in which is suspended or retained any stable absorbent or capillary material, saturated with hydro-carbon liquid through which air or gases are passed for carbureting. Patent i. Claims for Inventions in the Chemical 18 Very little information about the nature of the new inventions can be had by a study of these patent claims. I some of the claimants rely believe that words were invented to cor ideas? Issued November 3. 83,589-EXTRACTING SACCHARINE MATTERS PROM MALT.William Anheuser, St. Louis, Mo. Antedated October 28, 1868. Isan, 1st. The process of forcing a direct current of steam, water, or compressed air into a tight compartment, containing the malt, for the purpose of pressing the saccharine juice from the malt. 2. The application of a suction apparatas to secure a ready issue of the Raccharine liquor, either separate or in combination with the device specified in the first claim. 83,615.-COMPOUND FOR KILLING INSECTS ON TREES.-H. D. Flower, Chicago, Ill. 1 ch... the ingredients herein named, compounded and applied substantially as and for the purpose set forth. 83,643.-MANUFACTURE OF OXYD OF ZINC FROM SULPHURETTED ORES.-David Lees, Blair county, Pa. I claim the application of a hot blast, substantially in the manner and by the process above described, to the manufacture of oxyd of zinc, whereby the oxyd is always formed in an oxydizing atmosphere, and at a temperature sufficiently elevated to decompose all injurious products. 83,683.-COMPOSITION FOR THE MANUFACTURE OF SAFETY AND OTHER FRICTION MATCHES.-William Austin, London England. I calm ist. The manufacture of match-igniting chemicals and ingredi 20. I claim a carbureting chamber, placed in the gas-holder tank, arranged to receive and distribute hydro-carbon liquid, through which air and gases are forced, for the purpose set forth. 83,758.-PROCESS OF PRESERVING TIMBER FROM. DECAY.Charles Brown, Albemarle county, Va. material or materials substantially as described. 83,786.-PROCESS OF RECOVERING THE MATERIALS OF WORNOUT PRINTERS' ROLLERS.-Joseph H. Osgood, Peabody, Ichim preserving or lapidifying "wood, in the manner and with the Mass. I claim the process for utilizing the ingredients of discarded roller.om NEW PUBLICATIONS. A PRACTICAL TREATISE ON MST:LURGY: Adapted from the last Ger- THE VARIATION OF ANIMALS AND PLANTS UNDER DOMESTICATION. By A SYSTEM OF INSTRUCTION IN THE PRACTICAL USE OF THE BLOWPIPE: 348 American Supplement. Dec., 1909. The closet commode is a very proper thing to have in every house. pamphlet will do goed in making more public the useful, sisorbing and deodorizing power of dry earth. Second nuisances of privies when the use of water is impracticable. The subthose engaged in the examination of Metallic combinations. Edition. With an sppendix and a copious index, by G. W. Plymp-ject is evidently a lobby with Mr. Waring, and he thinks an earth ton, A. M., Professor of Physical Scictice of the Polytechnic InstituNew York: D. Van Nostrand. tion, Brooklyn. Pp 298. $2. Trus is a compilation from the German of Seher ver and Plattner, and the title indicates what it was intended for. The first edition was chosen for a text-book by Professor Plympton and other teachers. This second edition has been carefully revised, corrected, and enlarged, and is now without doubt an accurate presentation and exposition of the uses of the Blowpipe, MICROSCOPIC EXAMINATIONS OF BLOOD; AND VEGETATIONS FOUND IN LIGHT: Its Influence on Life and Health. It By FORBES WINSLOW, M.D., The object of this book is to show the Importance of Light as a A TREATISE ON OPTICS: Or Light and Sight Theoretically and Practi- THE Author says in his preface: "It is hoped that this treatise will With nu How CROPS GROW: A Treatise on the Chemical Composition, Structure PROF, JOH SON, although a young man, is already known to the pub- A TREATISE ON PHYSIOLOGY AND HYGIENE: For Schools. Families, and Aton. Pamphlets. EARTH CLOSETS: How to make them and how to use them. By Geo. The Earth Closet is an invention by which dry earth, in a ne pow- PAPER ON BUILDING STONE. By Charles H. Porter, M.D. To the New DR. PORTER discourses of good and bad building stones, the causes of f THE chemical papers in this number are: 1. On the Molecular trac- The conclusion to which the author (Prof. Henry Wurtz) arrives is that ITEMS AND NOTES. DR. R. P. STEVENS, who has for the past six months been employed in the exploration of the gold district of Guiana. Venezuela, S. A visited this city during November. He reports the new gold discoveries to be of great importance. His memory is kept green at our office by the skin of a boa 18 feet in length, and the skin of a South America leopard. E. W. DIMOND has entered upon his duties as Prof. of Chemistry in Dartmonth College He will give a Course of Lectures on Pharmaceutical and Agricultural Chemistry in addition to the usual routine. DR. C. F. CHANDLER, Chemist to the Metropolitan Board of Health, has recently, by analysis, &c.. examined the Croton water, and the breadstuffs used in this city. He reports favorably of the quality of both. E. P. HARRIS, lately of Beloit, Wis., has been appointed Prof of Chemistry in Amherst College, to succeed W. S. Clark, now President of the Mass. Agricultural College. H. F. WALLING, of New York, will commence his duties as Pret : Civil and Topographical Engineering, with the new year, at Lafayette College. Easton, Pa. He intends to prepare models of the principal cost and iron mines, and give special prominence in his instruction to mining engineering. C. H. HITCHCOCK, recently appointed State Geologist of New Hamp shire, directs his attention chiefly to the mining interest, and has cor. menced his work by a preliminary examination of the gold district in the neighborhood of Lisbon. Prof. Hitchcock has also recently been added to the faculty of Dartmouth College. Next summer he will instruct a class in field geology. C. A. GOESSMAN, Chemist of Salt Works at Salina, N. Y., is elected Prof of Chemistry in the Mass. Agricultural College. E. W. Root, late Assistant in the School of Mines of Columbia Col lege, has been appointed Prof of Agricultural Chemisty in Hamten College. We regret to learn that illness keeps him away from his new duties. DR. G. L. GOODALE, of Saco, Me., is the new Professor of Chemistry in Bowdoin College. A. P. ROCKWELL. Prof. of Mining in Yale College, is also Prof. of Mining Engineering in the Mass. Institute of Technology. A. M. EDWARDS, as Prof. of Chemistry, sncceeds Dr. Chandler in the College of Pharmacy, and C. P. Stone in the Medical College for Women, all of this city. PROFESSOR JOHN LE CONTE has left the University of South C to take the professorship of physics in the State University fornia. Cali . |